SALT ADDITEVES EFFECTS ON THE ACTIVATION PARAMETERS OF HETEROLYTIC REACTIONS

Authors

DOI:

https://doi.org/10.30888/2415-7538.2020-18-01-020

Keywords:

 activation parameters, normal salt effect, catalysis, activation enthalpy, activation entropy, unimolecular heterolysis

Abstract

Additives of salts are powerful tools of a reaction’s run. They can change the rates and stereochemistry of the reactions, alter the directions of reagents’ attacks. But their effects on activation parameters of the reactions have not studied yet. In the

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References

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Dvorko G. F., Ponomareva E. A., Ponomarev M. E., Stambirsky M. V., (2007) Nature of salt effects and mechanism of covalent bond heterolysis. Progress in Reaction Kinetics and Mechanism. 32(2), 73–118.

Ponomareva E.A., Vasylkevich A.I., Tarasenko P.V., Dvorko G. F., (1988) Kinetics and Mechanism of Monomolecular Heterolysis of Cage Compounds. VI. Dehydrobromination of 2-bromo-2-methyladamantane in acetonitrile. Russian Journal of OrganicChemistry. 24(3), 549-557.

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Dvorko G. F., Ponomareva E. A., Ponomarev M. E., Stambirsky M. V. Nature of salt effects and mechanism of covalent bond heterolysis. Progress in Reaction Kinetics and Mechanism. 2007. Vol.32, № 2. P. 73–118. DOI: 10.3184/146867807X227471

Пономарёва Э.А.. Василькевич А.И., Тарасенко П.В., Дворко Г.Ф. Кинетика и механизм мономолекулярного гетеролиза каркасных соединений. VI. Дегидробромирование 2-бром-2-метиладамантана в ацетонитриле. Журнал органической химии. 1988. Т.24, Вып.3. C.549-557.

Published

2021-01-01

How to Cite

Пономарьов, М., Шендрик, А., & Каменська, Т. (2021). SALT ADDITEVES EFFECTS ON THE ACTIVATION PARAMETERS OF HETEROLYTIC REACTIONS. Scientific Look into the Future, 1(18-01), 88–92. https://doi.org/10.30888/2415-7538.2020-18-01-020

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