SYNTHESIS, STOICHIOMETRY AND STRUCTURE OF HETEROLIGAND TETRAFLUOROBORATE COMPLEXES OF CU(ІІ), ZN(ІІ) AND CD(ІІ) WITH BENZOTRIAZOLE

Authors

  • Marina Vladimirovna Shestakova Odessa National Maritime University http://orcid.org/
  • Natalya Pavlovna Galaktionova Odessa National Maritime University http://orcid.org/
  • Aleksandr Nikolaevich Chebotarev Odessa National University. I.I. Mechnikov http://orcid.org/

DOI:

https://doi.org/10.30888/2415-7538.2018-11-03-035

Keywords:

synthesis, tetrafluoroborate, benzotriasole, heteroligand complex

Abstract

The tetrafluoroborate heteroligand complexes of Cu (ІІ), Zn (ІІ) and Cd (ІІ) with benzotriasole have been synthesized. The dependence of the synthesised compounds stoichiometry on the conditions of synthesis has been established. The investigation of the

Metrics

Metrics Loading ...

References

Tomlinson A.A.G. Crystal and molecular structure of aquobis (ethylenediamine)(tetrafluoroborate) nickel (II) tetrafluoroborate. J. Chem. Soc. Dalton Trans., 1972, no15, pp. 1671-1674. http://dx.doi.org/10.1039/dt9720001671

Foley J., Kennefick D., Phelan D., Tyagi S., Hathaway B. The crystal structure and electronic properties of catena–bis–(2,2’– bipyridyl)--tetrafluoroborato-copper (II) tetrafluoroborate and catena–bis(2,2’-bipyridyl)––perchlorato–copper (II) perchlorate. J. Chem. Soc. Dalton Trans., 1983, no 21, pp. 2333-2338. http://dx.doi.org/10.1039/dt9830002333

Verrosi I.M., Zanoli F.A. Coordination behaviour of 2-aminobenzophenone toward the copper (II) ion in the presence of low-coordinating coligands. Inorg. chim. Acta, 1985, vol. 105, no 1, pp. 13-17. http://dx.doi.org/10.1016/s0020-1693(00)85240-8

Khorunov V. F. , Sabadash O. M. , Chebotarev A. N. , Shestakova M. V. Complex tetrafluoroborate compounds as activators of fluxes for low-temperature soldering of aluminium // Lectures and Posters of the 5th International Conference "Brazing, High Temperature Brazing and Diffusion Welding". Aachen. - 1998. - P. 200-201.

Хорунов В.Ф. Пайка алюминия и разнородных материалов с комплексными тетрафтороборатами / В.Ф. Хорунов, О.М. Сабадаш, А.Н. Чеботарев, М.В. Шестакова // Тр. 1ой Международной научно-практической конференции “Защита окружающей среды, здоровье, безопасность в сварочном производстве”. – Одесса, 2002 – С. 665-670.

Шестакова М.В., Чеботарев А.Н. Состав и строение комплексных тетрафтороборатов Zn(II) с изомерными фенилендиаминами // Вісник Одеського національного університету. - 2015. - Т. 20, № 3. - С. 76-79.

Чеботарев, А.Н. К проблеме состояния тетрафтороборат-иона в комплексных соединениях с азотсодержащими органическими основаниями / А.Н. Чеботарев, М.В. Шестакова, Т.М. Щербакова // Координационная химия. – 2002. – Т. 28, № 2. – С. 140-143.

Shestakova M.V., Chebotarev A.N. Research of composition and structure of complex Cd(II) tetrafluoroborates with phenylenediamines // Праці Одеського політехнічного університету. - 2016. - №1. - С. 101-105.

Tomlinson A.A.G. Crystal and molecular structure of aquobis (ethylenediamine)(tetrafluoroborate) nickel (II) tetrafluoroborate. J. Chem. Soc. Dalton Trans., 1972, № 15, p. 1671-1674. http://dx.doi.org/10.1039/dt9720001671

Foley J., Kennefick D., Phelan D., Tyagi S., Hathaway B. The crystal structure and electronic properties of catena–bis–(2,2’– bipyridyl)--tetrafluoroborato-copper (II) tetrafluoroborate and catena–bis(2,2’-bipyridyl)––perchlorato–copper (II) perchlorate. J. Chem. Soc. Dalton Trans., 1983, № 21, p. 2333-2338. http://dx.doi.org/10.1039/dt9830002333

Verrosi I.M., Zanoli F.A. Coordination behaviour of 2-aminobenzophenone toward the copper (II) ion in the presence of low-coordinating coligands. Inorg. chim. Acta, 1985, vol. 105, № 1, p. 13-17. http://dx.doi.org/10.1016/s0020-1693(00)85240-8

Khorunov V.F., Sabadash O.M., Chebotarev A.N., Shestakova M.V. Complex tetrafluoroborate compounds as activators of fluxes for low-temperature soldering of aluminium // Lectures and Posters of the 5th International Conference "Brazing, High Temperature Brazing and Diffusion Welding". Aachen. - 1998. - P. 200-201.

Khorunov V. F., Sabadash O. M., Chebotarev A. N., Shestakova M. V. Payka alumimiya i raznorodnuch materialov s komplexnumi tetraftoroboratami [Soldering of aluminium and dissimilar materials with complex tetrafluoroborates]. Trudu 1 Megdunarodnoy nauchno-practicheskoy conferensii “Zashita okrugayushey sredu, zdorovye, bezopasnost v svarochnom proizvodsnve” [Proceedings of the 1st International Scientific and Practical Conference "Environmental Protection, Health, Safety in Welding Production"]. – Odessa, 2002 – P. 665-670.

Shestakova M.V., Chebotarev A.N. Sostav i stroyeniye complexnukh tetraftoroboratov Zn(II) s isomernumi phenylendiaminami [Stoichiometry and structure of tetrafluoroborate complexes of Zn(II) with isomeric phenylendiamines]// Visnuk Odeskogo nasionalnogo universutetu [Odesa National University Herald]. - 2015. - V. 20, № 3. - P 76-79.

Chebotaryov A.N., Shestakova M.V., Scherbakova T.M. K probleme sostoyaniya tetraftoroborat-iona v complexnukh soedineniyakh s azotsodergashimi organicheskimi osnovaiyami [To the tetrafluroborate-ion state problem in complexes with nitrogen organic bases]. Coordinasionaya chimiya [Russian Journal of Coordination Chemistry], 2002, vol. 28, № 2, p. 140-143. http://dx.doi.org/10.1023/A:1014288219106

Shestakova M.V., Chebotarev A.N. Research of composition and structure of complex Cd(II) tetrafluoroborates with phenylenediamines // Pratsi Odeskogo polytechnichnogo universutetu [Оdes’kyi Politechnichnyi Universytet Pratsi] - 2016. - №1. - P. 101-105.

Published

2018-11-30

How to Cite

Shestakova, M. V., Galaktionova, N. P., & Chebotarev, A. N. (2018). SYNTHESIS, STOICHIOMETRY AND STRUCTURE OF HETEROLIGAND TETRAFLUOROBORATE COMPLEXES OF CU(ІІ), ZN(ІІ) AND CD(ІІ) WITH BENZOTRIAZOLE. Scientific Look into the Future, 3(11-03), 107–111. https://doi.org/10.30888/2415-7538.2018-11-03-035

Issue

Section

Articles

Most read articles by the same author(s)