Дегідратації біоетанолу (ПАЛИВНОГО ЕТАНОЛУ)

Автор(и)

  • Petr Nikolaevich Bojko Національний університет харчових технологій http://orcid.org/
  • Nikolaj Vasilevich Bondar Національний університет харчових технологій http://orcid.org/
  • Anatolij Mihajlovich Kuc Національний університет харчових технологій http://orcid.org/

DOI:

https://doi.org/10.30888/2415-7538.2018-08-01-003

Ключові слова:

біоетанол, дегідратація, адсорбційний метод, молекулярні сита, азеотропічний метод

Анотація

В статті розглядаються технодогії зневоднення при виробництві ьіоетанолу (паливного етанолу)

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Посилання

K. Kupiec and A. Kubala, Dehydration of ethanol used as a fuel addi-tive. Environment Protection Engineering, 2006. 32(1): p. 151–159.

S. Kumar, N. Singh, and R. Prasad, Anhydrous ethanol: A renewable source of energy. Renewable and Sustainable Energy Reviews, 2010. 14(7): p. 1830–1844.

S. Al-Asheh, F. Banat, and N. Al-Lagtah, Separation of ethanol-water mixtures using molecular sieves and biobased adsorbents. Chemical Engineering Research and Design, 2004. 82(7): p. 855–864.

J.S. Jeong, H. Jeon, K.M. Ko, B. Chung, and G.W. Choi, Production of anhydrous ethanol using various PSA (Pressure Swing Adsorption) processes in pilot plant. Renewable Energy, 2012. 42: p. 41–45.

J.S. Jang, Y.K. Cho, G.T. Jeong, and S.K. Kim, Optimization of sacchari-fication and ethanol production by simultaneous saccharification and fermentation (SSF) from seaweed, Saccharina japonica. Bioprocess and Biosystems Engineering, 2012. 35(1–2): p. 11–18.

J.S. Jeong, B.U. Jang, Y.R. Kim, B.W. Chung, and G.W. Choi, Production of dehydrated fuel ethanol by pressure swing adsorption process in the pilot plant. Korean Journal of Chemical Engineering, 2009. 26(5): p. 1308–1312.

M. Simo, S. Sivashanmugam, C.J. Brown, and V. Hlavacek, Adsorption/desorption of water and ethanol on 3A zeolite in near-adiabatic fixed bed. Industrial and Engineering Chemistry Research, 2009. 48(20): p. 9247–9260.

C.D. Tereck. Technology developments in Psa ethanol dehydration. 2008.

K. Kupiec, J. Rakoczy, L. Zieliński, and A. Georgiou, Adsorption-desorption cycles for the separation of vapour-phase ethanol/water mixtures. Adsorption Science and Technology, 2008. 26(3): p. 209–224.

T. Yamamoto, Y.H. Kim, B.C. Kim, A. Endo, N. Thongprachan, and T. Ohmori, Adsorption characteristics of zeolites for dehydration of ethanol: Evaluation of diffusivity of water in porous structure. Chemical Engineering Journal, 2012. 181–182: p. 443–448.

M.R. Ladisch, M. Voloch, J. Hong, P. Bienkowski, and G.T. Tsao, Cornmeal adsorber for dehydrating ethanol vapors. Industrial & Engineering Chemistry Process Design and Development, 1984. 23(3): p. 437–443.

H. Chang, X.G. Yuan, H. Tian, and A.W. Zeng, Experimental study on the adsorption of water and ethanol by cornmeal for ethanol dehy-dration. Industrial and Engineering Chemistry Research, 2006. 45(11): p. 3916–3921.

T.J. Benson and C.E. George, Cellulose based adsorbent materi-als for the dehydration of ethanol using thermal swing adsorption. Adsorption, 2005. 11(1 SUPPL.): p. 697–701.

C. Boonfung and P. Rattanaphanee, Pressure swing adsorption with cassava adsorbent for dehydration of ethanol vapor. World Academy of Science, Engineering and Technology, 2010. 71: p. 637–640.

J.A. Quintero and C.A. Cardona, Ethanol dehydration by adsorp-tion with starchy and cellulosic materials. Industrial and Engineering Chemistry Research, 2009. 48(14): p. 6783–6788.

H. Chang, X. Yuan, and A. Zeng, Adsorption capability of biomass for ethanol dehydration. Huagong Xuebao/Journal of Chemical Industry and Engineering (China), 2004. 55(2): p. 309–312.

S. Young, LXXIII. - The preparation of absolute alcohol from strong spirit. Journal of the Chemical Society, Transactions, 1902. 81: p. 707–717.

V. Gomis, A. Font, R. Pedraza, and M.D. Saquete, Isobaric vapor-liq-uid and vapor-liquid-liquid equilibrium data for the system water + ethanol + cyclohexane. Fluid Phase Equilibria, 2005. 235(1): p. 7–10.

V. Gomis, A. Font, R. Pedraza, and M.D. Saquete, Isobaric vapor-liq-uid and vapor-liquid-liquid equilibrium data for the water-ethanol-hexane system. Fluid Phase Equilibria, 2007. 259(1 SPEC. ISS.): p. 66–70.

V. Gomis, A. Font, and M.D. Saquete, Vapour-liquid-liquid and vapour-liquid equilibrium of the system water + ethanol + heptane at 101.3 kPa. Fluid Phase Equilibria, 2006. 248(2): p. 206–210.

V. Gomis, R. Pedraza, O. Francés, A. Font, and J.C. Asensi, Dehydration of ethanol using azeotropic distillation with isooctane. Industrial and Engineering Chemistry Research, 2007. 46(13): p. 4572–4576.

A. Font, J.C. Asensi, F. Ruiz, and V. Gomis, Application of isooctane to the dehydration of ethanol. Design of a column sequence to obtain absolute ethanol by heterogeneous azeotropic distillation. Industrial and Engineering Chemistry Research, 2003. 42(1): p. 140–144.

C. Black, Distillation modeling of ethanol recovery and dehydration processes for ethanol and gasohol. Chemical Engineering Progress, 1980. 76(9): p. 78–85.

A.M. Al-Amer, Investigating polymeric entrainers for azeotropic dis-tillation of the ethanol/water and MTBE/methanol systems. Industrial and Engineering Chemistry Research, 2000. 39(10): p. 3901–3906.

F.M. Lee and R.H. Pahl, Solvent screening study and conceptual extractive distillation process to produce anhydrous ethanol from fer-mentation broth. Industrial and Engineering Chemistry Process Design and Development, 1985. 24(1): p. 168–172.

M.F. de Figueirêdo, B.P. Guedes, J.M.M. de Araújo, L.G.S. Vasconcelos, and R.P. Brito, Optimal design of extractive distillation columns-A systematic procedure using a process simulator. Chemical Engineering Research and Design, 2011. 89(3): p. 341–346.

M.R.W. Maciel and R.P. Brito, Evaluation of the dynamic behavior of an extractive distillation column for dehydration of aqueous ethanol mix-tures. Computers and Chemical Engineering, 1995. 19(SUPPL. 1): p. 405–408.

Y. Nishi, Vapor-liquid equilibrium relations for the system accompa-nied by hypothetical chemical reaction containing salt. J Chem Eng Jap, 1975. 8(3): p. 187–191.

D. Jaques and M.A. Galan, Isobaric LVE data for alcohol-water systems saturated with a salt which appear to contradict the Gibbs-Konovolov theorem. Chemical Engineering Science, 1980. 35(8): p. 1803–1804.

M.A. Galan, M.D. Labrador, and J.R. Alvarez, Salt effect in liquid-vapor equilibrium: Ethanol-water system saturated with strontium bromide, barium nitrate, and strontium nitrate. Journal of Chemical and Engineering Data, 1980. 25(1): p. 7–9.

T.C. Tan, W.K. Teo, and H.C. Ti, Vapor liquid equilibria of ethanol-water system saturated with glucose at subatmospheric pressures. Chemical Engineering Research and Design, 1988. 66(1): p. 75–83.

A. Grohan, Apparatus for producing anhydrous ethyl alcohol diretly from mashes, 1934: US Patent.

W.F. Furter, Extractive distillation by salt effect. Chemical Engineering Communications, 1992. 116: p. 35–40.

V.V. Namboodiri and L.M. Vane, High permeability membranes for the dehydration of low water content ethanol by pervaporation. Journal of Membrane Science, 2007. 306(1–2): p. 209–215.

P. Peng, B. Shi, and Y. Lan, A review of membrane materials for etha-nol recovery by pervaporation. Separation Science and Technology, 2011. 46(2): p. 234–246.

X. Zhan, J. Li, J. Huang, and C. Chen, Ethanol perm-selective membranes by pervaporation. Progress in Chemistry, 2008. 20(9): p. 1416–1426.

P. Innachitra and S. Chinchiw, Ethanol-water separation by pervapora-tion using silicone and polyvinyl alcohol membranes. Songklanakarin Journal of Science and Technology, 2006. 28(5): p. 1109–1119.

A.M. Toikka, E.L. Aksenova, and Y.P. Kuznetsov, Comparative anal-ysis of open evaporation and pervaporation in the ternary system water-ethanol-isopropanol. Russian Journal of Applied Chemistry, 2001. 74(6): p. 933–938.

X. Feng and R.Y.M. Huang, Liquid Separation by Membrane Pervaporation: A Review. Industrial and Engineering Chemistry Research, 1997. 36(4): p. 1048–1066.

J.G. Wijmans and R.W. Baker, The solution-diffusion model: A review.Journal of Membrane Science, 1995. 107(1–2): p. 1–21.

S. Amnuaypanich and N. Kongchana, Natural rubber/poly(acrylic acid) semi-interpenetrating polymer network membranes for the pervaporation of water-ethanol mixtures. Journal of Applied Polymer Science, 2009. 114(6): p. 3501–3509.

S. Amnuaypanich, J. Patthana, and P. Phinyocheep, Mixed matrix membranes prepared from natural rubber/poly(vinyl alcohol) semi-interpenetrating polymer network (NR/PVA semi-IPN) incorporating with zeolite 4A for the pervaporation dehydration of water-ethanol mixtures. Chemical Engineering Science, 2009. 64(23): p. 4908–4918.

S.B. Teli, G.S. Gokavi, and T.M. Aminabhavi, Novel sodium alginate-poly(N-isopropylacrylamide) semi-interpenetrating polymer network membranes for pervaporation separation of water + ethanol mixtures. Separation and Purification Technology, 2007. 56(2): p. 150–157.

C.L. Chang and M.S. Chang, Preparation of composite membranes of functionalised silicone polymers and PVDF for pervaporation of ethanol-water mixture. Desalination, 2002. 148(1–3): p. 39–42.

E. Oikawa, K. Nozawa, T. Kaneko, and T. Aoki, Pervaporation of non-aqueous ethanol azeotropes through interpenetrating polymer net-work membranes prepared from poly(4-vinylpyridine) and poly(vinyl alcohol). Journal of Applied Polymer Science, 2001. 82(11): p. 2729–2738.

A.L. Buyanov, L.G. Revel’Skaya, Y.P. Kuznetzov, and A.K. Khripunov, Cellulose-poly(acrylamide-acrylic acid) interpenetrating polymer network membranes for the pervaporation of water-ethanol mixtures.II. Effect of ionic group contents and cellulose matrix modification.Journal of Applied Polymer Science, 2001. 80(9): p. 1452–1460.

A.L. Buyanov, L.G. Revel’skaya, Y.P. Kuznetzov, and A.S. Shestakova, Cellulose-poly(acrylamide or acrylic acid) interpenetrating polymer network membranes for the pervaporation of water-ethanol mixtures.Journal of Applied Polymer Science, 1998. 69(4): p. 761–769.

T. Miyata, J.I. Higuchi, H. Okuno, and T. Uragami, Preparation of polydimethylsiloxane/polystyrene interpenetrating polymer network membranes and permeation of aqueous ethanol solutions through the membranes by pervaporation. Journal of Applied Polymer Science, 1996. 61(8): p. 1315–1324.

L. Liang and E. Ruckenstein, Pervaporation of ethanol-water mixtures through polydimethylsiloxane-polystyrene interpenetrating polymer network supported membranes. Journal of Membrane Science, 1996. 114(2): p. 227–234.

L. Liang and E. Ruckenstein, Polyvinyl alcohol-polyacrylamide inter-penetrating polymer network membranes and their pervaporation characteristics for ethanol-water mixtures. Journal of Membrane Science, 1995. 106(1–2): p. 167–182.

Y.K. Lee, T.M. Tak, D.S. Lee, and S.C. Kim, Cationic/anionic interpen-etrating polymer network membranes for the pervaporation of etha-nol-water mixture. Journal of Membrane Science, 1990. 52(2): p. 157–172.

J.W. Rhim and R.Y.M. Huang, Prediction of pervaporation separa-tion characteristics for the ethanol-water-nylon-4 membrane system. Journal of Membrane Science, 1992. 70(2–3): p. 105–118.

T. Jin, Y. Ma, W. Matsuda, Y. Masuda, M. Nakajima, K. Ninomiya, T. Hiraoka, Y. Daiko, and T. Yazawa, Ethanol separation from etha-nol aqueous solution by pervaporation using hydrophobic meso-porous silica membranes. Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan, 2011. 119(1391): p. 549–556.

P. Peng, B. Shi, and Y. Lan, Preparation of PDMS-silica nanocomposite membranes with silane coupling for recovering ethanol by pervapora-tion. Separation Science and Technology, 2011. 46(3): p. 420–427.

Y. Ma, J. Wang, and T. Tsuru, Pervaporation of water/ethanol mixtures through microporous silica membranes. Separation and Purification Technology, 2009. 66(3): p. 479–485.

H. Ahn, H. Lee, S.B. Lee, and Y. Lee, Pervaporation of an aqueous ethanol solution through hydrophilic zeolite membranes. Desalination, 2006. 193(1–3): p. 244–251.

V.T. Magalad, G.S. Gokavi, M.N. Nadagouda, and T.M. Aminabhavi, Pervaporation separation of water-ethanol mixtures using organic-inorganic nanocomposite membranes. Journal of Physical Chemistry C, 2011. 115(30): p. 14731–14744.

V.T. Magalad, A.R. Supale, S.P. Maradur, G.S. Gokavi, and T.M. Aminabhavi, Preyssler type heteropolyacid-incorporated highly water-selective sodium alginate-based inorganic-organic hybrid mem-branes for pervaporation dehydration of ethanol. Chemical Engineering Journal, 2010. 159(1–3): p. 75–83.

B.P. Tripathi, M. Kumar, A. Saxena, and V.K. Shahi, Bifunctionalized organic-inorganic charged nanocomposite membrane for pervapo-ration dehydration of ethanol. Journal of Colloid and Interface Science, 2010. 346(1): p. 54–60.

T. Uragami, H. Matsugi, and T. Miyata, Pervaporation characteristics of organic-inorganic hybrid membranes composed of poly(vinyl alco-hol-co-acrylic acid) and tetraethoxysilane for water/ethanol separa-tion. Macromolecules, 2005. 38(20): p. 8440–8446.

M.S. Schehlmann, E. Wiedemann, and R.N. Lichtenthaler, Pervaporation and vapor permeation at the azeotropic point or in the vicinity of the LLE boundary phases of organic/aqueous mixtures. Journal of Membrane Science, 1995. 107(3): p. 277–282.

D. Van Baelen, B. Van Der Bruggen, K. Van Den Dungen, J. Degreve, and C. Vandecasteele, Pervaporation of water-alcohol mixtures and acetic acid-water mixtures. Chemical Engineering Science, 2005. 60(6): p. 1583–1590.

T.A. Peters, C.H.S. Poeth, N.E. Benes, H.C.W.M. Buijs, F.F. Vercauteren, and J.T.F. Keurentjes, Ceramic-supported thin PVA pervaporation membranes combining high flux and high selectivity; contradicting the flux-selectivity paradigm. Journal of Membrane Science, 2006. 276(1– 2): p. 42–50.

R. Nóbrega, A.C. Habert, M.E.F. Garcia, R.J. Esposito, and C.P. Borges, Separation of ethanol/water mixtures by pervaporation through poly-vinylalcohol membranes, in: Proceedings of 3rd International Conference on Pervaporation Processes in the Chemical Industry. Bakish Materials Corporation, Englewood, NJ, USA, ,, 1988: p. 326–337.

C.K. Yeom, S.H. Lee, and J.M. Lee, Pervaporative permeations of homologous series of alcohol aqueous mixtures through a hydrophilic membrane. Journal of Applied Polymer Science, 2001. 79(4): p. 703–713.

Y.Q. Dong, L. Zhang, J.N. Shen, M.Y. Song, and H.L. Chen, Preparation of poly(vinyl alcohol)-sodium alginate hollow-fiber composite mem-branes and pervaporation dehydration characterization of aqueous alcohol mixtures. Desalination, 2006. 193(1–3): p. 202–210.

S.S. Gaykawad, Y. Zha, P.J. Punt, J.W. van Groenestijn, L.A.M. van der Wielen, and A.J.J. Straathof, Pervaporation of ethanol from lignocellu-losic fermentation broth. Bioresource Technology, 2013. 129: p. 469–476.

W. Kaminski, J. Marszalek, and A. Ciolkowska, Renewable energy source-Dehydrated ethanol. Chemical Engineering Journal, 2008. 135(1–2): p. 95–102.

Опубліковано

2018-01-31

Як цитувати

Bojko, P. N., Bondar, N. V., & Kuc, A. M. (2018). Дегідратації біоетанолу (ПАЛИВНОГО ЕТАНОЛУ). Науковий погляд у майбутнє, 2(08-01), 13–32. https://doi.org/10.30888/2415-7538.2018-08-01-003

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